Silicon Carbide (siblings)
Black Silicon Carbide (C / CP / Refractory)
CAS: 409-21-2
Black silicon carbide is synthesized from quartz sand (SiO₂) and petroleum coke (C) in an Acheson electric resistance furnace at >1800°C. SiC content ≥98.5%, with a slightly higher Fe₂O₃ and free-C tail than the green grade — the difference that puts black SiC at a 15–25% price discount and makes it the workhorse abrasive and refractory raw material across coated abrasives, foundry blast media, ceramic-bonded grinding wheels, kiln-furniture batters, and steelmaking deoxidizer. Supplied in coarse particle-size sand (F14–F220, ISO 8486-1 / GB/T 2481.2), in P-grit for coated-abrasive papers and belts (P12–P2500), and in refractory aggregates 0–1 mm / 1–3 mm at graded SiC purity 80% to 98%.
Specifications
| CAS Number | 409-21-2 |
| SiC Content | ≥98.5% (abrasive) / 80–98% (refractory) |
| Free Carbon | ≤0.20% |
| Fe₂O₃ | ≤0.20% |
| Particle Size — Sand | F14 – F220 (ISO 8486-1, GB/T 2481.2) |
| Particle Size — P-grit | P12 – P2500 (FEPA 43-1984) |
| Particle Size — Refractory | 0–1 mm / 1–3 mm / 200F / 325F |
| Bulk Density (LPD) | 1.30 – 1.64 g/cm³ |
| Mohs Hardness | 9.2 |
| Crystal System | α-SiC (hexagonal) |
| Colour | Black to dark grey |
| Magnetic Substance | JB/T 6570-2007 |
| Packaging | 25 kg PP bag / 1000 kg jumbo bag / 25 t bulk |
Applications
- Coated abrasives — sand belts, sandpaper, sand cloth for woodworking and metal finishing
- Vitrified bonded grinding wheels for general grinding (cast iron, low-carbon steel, brass)
- Foundry shot-blast and surface preparation media
- Refractory aggregate for steel furnace linings, glass tank crowns, ceramic kiln furniture
- Steelmaking deoxidizer and slag conditioner (SiC briquette)
- Wire-saw slurry for silicon wafer cutting (photovoltaic and semiconductor)
- Functional filler in carbon-bonded SiC bricks (slide-gate plates, runners)
Key Features
- Lowest cost-per-kg SiC abrasive — 15–25% below green SiC at equivalent grit
- Mohs 9.2 hardness and low thermal expansion (4.4 × 10⁻⁶ /°C) — second only to diamond, B₄C in industrial abrasives
- Service to 1450°C in oxidizing atmospheres, 1600°C in inert/reducing
- Full FEPA / ISO / GB / JIS / FEPA-P grit standards coverage in one supplier
- RoHS / REACH / SVHC-clean — non-toxic, non-hazardous
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Technical Details
Overview
Black silicon carbide (black SiC, C-grade, carborundum) is the workhorse industrial SiC abrasive — synthesised by Acheson carbothermal reduction of quartz sand and petroleum coke at >1800°C, then crushed, acid-leached, dried, sieved, and classified into FEPA / ISO / GB / FEPA-P particle-size standards. SiC content ≥98.5%, with slightly higher Fe₂O₃ and free-C tail than the green grade — the difference that puts black SiC at a 15–25% per-kg discount and makes it the dominant choice for coated abrasives, foundry blast media, ceramic-bonded grinding wheels on general steels, refractory aggregate for high-temperature furnace linings, and steelmaking deoxidiser briquettes.
Three product forms cover the demand: F14–F220 particle-size sand for grinding wheels and shot-blast, P12–P2500 P-grit for coated abrasives (sand belts, sandpaper, sand cloth, polishing pads), and 0–1 mm / 1–3 mm / 200F / 325F refractory aggregates at graded SiC purity from 80% to 98% for kiln-furniture batters, steel-furnace linings, glass tank crowns, and ceramic kiln furniture.
The compound is a black to dark-grey crystalline solid, α-SiC (hexagonal) crystal system, Mohs hardness 9.2, density 3.21 g/cm³ (theoretical), bulk density 1.30–1.64 g/cm³ depending on grit. Service temperature 1450°C in oxidising atmospheres and 1600°C in inert or reducing atmospheres. Non-toxic, non-hazardous, RoHS / REACH / SVHC clean.
Technical Specifications
| Property | Value |
|---|---|
| Chemical Name | Silicon Carbide (Black Grade) |
| CAS Number | 409-21-2 |
| SiC Content — Abrasive | ≥98.50% |
| SiC Content — Refractory | ≥80% / ≥85% / ≥90% / ≥95% / ≥98% (five grades) |
| Free Carbon | ≤0.20% (abrasive); ≤0.20–0.40% (refractory) |
| Fe₂O₃ | ≤0.20% (abrasive); ≤0.20–0.30% (refractory) |
| Crystal System | α-SiC (hexagonal) |
| Colour | Black to dark grey |
| Particle Size — Sand | F14, F16, F20, F22, F24, F30, F36, F40, F46, F54, F60, F70, F80, F90, F100, F120, F150, F180, F220 (FEPA / ISO 8486-1 / GB/T 2481.2) |
| Particle Size — P-grit | P12, P16, P20, P24, P30, P36, P40, P50, P60, P80, P100, P120, P150, P180, P220, P240, P280, P320, P360, P400, P500, P600, P800, P1000, P1200, P1500, P1800, P2000, P2500 (FEPA 43-1984) |
| Particle Size — Refractory | 0–1 mm, 1–3 mm, 200F, 325F |
| Bulk Density LPD | 1.54–1.64 g/cm³ (F14); 1.30–1.40 g/cm³ (F220) |
| Mohs Hardness | 9.2 |
| Knoop Hardness | ~2480 HK |
| Density (theoretical) | 3.21 g/cm³ |
| Service Temperature | ≤1450°C (oxidising); ≤1600°C (inert/reducing) |
| Thermal Expansion | 4.4 × 10⁻⁶ /°C (25–1000°C) |
| Magnetic Substance | JB/T 6570-2007 |
| Standards | GB/T 2481.2-1998, ISO 8486-1:1996, JIS R6001-1998, FEPA 43-1984 |
| Packaging | 25 kg PP bag / 1000 kg jumbo bag / 25 t bulk |
Applications
Coated Abrasives
Sand belts, sandpaper, sand cloth, polishing pads for woodworking (P40–P320 typical), metal finishing (P80–P600), automotive body refinishing (P800–P2000), and decorative-substrate sanding. The P-grit cut is narrower than F-grit cut — coated-abrasive manufacturers specify P-grit to keep belt scratch-pattern uniform.
Vitrified-Bonded Grinding Wheels
General-purpose grinding wheels for cast iron, low-carbon steel, brass, aluminium, and non-ferrous metals. F46–F120 are most common. The vitrified ceramic bond is fired at 1100–1250°C; SiC's thermal expansion matches the bond well, giving high wheel durability. Use green SiC instead when grinding hardened tool steel or carbide tools.
Foundry Blast Media
Sand-blast for surface preparation before painting, plating, or thermal-spray coating. F30–F100 typical. SiC has 30–40% longer service life than corundum at equal blast intensity; recyclable 8–12 times before fragmenting below recoverable size.
Refractory Aggregate
Steel furnace linings (BOF, EAF, AOD), tundish nozzles, ladle linings — black SiC refractory at SiC ≥95% is fired into Si₃N₄- or SiC-bonded shapes that resist steel-slag attack. Glass tank crowns use SiC ≥95% refractory because molten glass corrodes alumina-silicate refractories rapidly above 1500°C. Ceramic kiln furniture (saggers, posts, plates) for fine-ceramic firing uses lower SiC content (80–90%) refractory because the service temperature is lower.
Steel Deoxidiser
SiC briquettes (60–70% SiC) are charged into steel ladles to deoxidise and recarburise; SiC reacts with FeO in the slag to release Si and C into the melt, displacing more expensive ferrosilicon and graphite electrodes.
Wire-Saw Slurry
Black SiC F600–F1200 in glycol carrier for cutting silicon wafers for photovoltaic ingots — lower cost than diamond wire-saw at equivalent throughput. (Note: semiconductor-grade wafer cutting uses green SiC for lower Fe contamination.)
Functional Filler
Carbon-bonded SiC refractory bricks (slide-gate plates, runners, blast-furnace troughs) — black SiC fills the major refractory body, carbon binder protects against thermal-shock spalling.
Selection Guide vs Green Silicon Carbide
Choose black SiC for: cost-sensitive bulk abrasives (sand-belt, sandpaper, sand-cloth manufacture); general-purpose vitrified-bonded grinding wheels (cast iron, low-carbon steel, brass); foundry shot-blast and surface preparation; refractory aggregate for steel furnace, glass tank, ceramic kiln; steelmaking deoxidiser; PV silicon-ingot wire-sawing.
Choose green SiC instead for: precision grinding wheels for tool steel and carbide tools; semiconductor-grade silicon wafer cutting; optical glass and sapphire polishing; stainless steel or titanium polishing where Fe contamination would disqualify black SiC.
The two are interchangeable in grit-standard specification (same F / P / refractory size codes), so process design can specify "black or green SiC F100" with downstream selection on cost. The price differential is typically 15–25% per kg in favour of black.
Equivalent Grades
- Washington Mills Carbolon — North American premium black SiC abrasive
- Saint-Gobain Sika ABR — European black SiC abrasive and refractory grades
- Grindwell Norton (India) — Indian premium supplier
- Elektrokarbon (Slovakia) — EU regional supplier
- Generic Chinese black SiC — commodity grade ≥98.5%, Shandong / Ningxia / Qinghai origin
SiC Content
≥98.5% (abrasive)
Particle Range
F14–F220 / P12–P2500 / 0–3 mm
Packaging
25 kg bag / 1 t jumbo / 25 t bulk
MOQ
1 t (sand) / 25 t (refractory)
Lead Time
2–3 weeks Asia / 5–7 weeks EU/NA
Origin
Shandong / Ningxia / Qinghai, China
Availability
In Stock